We are so excited that our recent work, showing a really cool and distinct approach to reducing small molecules like CO2 and ethylene, has been published in Angewandte Chemie! These findings show a really fascinating way that silylene ligands can template multimetallic redox reactions, and we think they may be extended more broadly to a variety of 3d metals. Congrats to students Jim Zhang ’18, Jason Ma ’18, and Anna Conley ’20 as well as collaborators Prof. Dani Kohen and Prof. Daron Janzen for their awesome work!!
This one has been a long time coming, but it has been worth the wait! Check out this fantastic work in Organometallics by Jim Zhang ’18, Teddy Donnell ’17, Paul Peterson ’18, and Mike Trenerry ’18, as well as our awesome collaborators Prof. Buck Taylor (and student Vanessa Eng) and Prof. Daron Janzen. We provide experimental and computational evidence for silicon-assisted CO2 cleavage by an anomalous insertion mechanism, highlighting another mechanism by which silicon can play a key role in transforming CO2.
— Organometallics (@Orgmet_ACS) November 12, 2019
Our ruthenium work has just been published! Check out Binh, Jim, and Jason’s awesome work demonstrating silylene-assisted hydride transfer to CO2.